Redox fundamentals: during an oxidation process, which of the following decreases for the species being oxidised?
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Anumber of electrons (electron count associated with the species)
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Boxidation number
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Cnumber of ions present in solution
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Dall (a), (b) & (c)
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Enone of these
Answer
Correct Answer: number of electrons (electron count associated with the species)
Explanation
Introduction / Context:Redox (reduction–oxidation) reactions are ubiquitous in corrosion, electrochemistry, metabolism, and industrial processes. A clear operational definition avoids confusion when balancing reactions or interpreting half-reactions.
Given Data / Assumptions:
- Oxidation defined as loss of electrons (OIL RIG: Oxidation Is Loss, Reduction Is Gain).
- Oxidation number is a bookkeeping device that typically increases upon oxidation.
Concept / Approach:When a species is oxidised, it donates electrons; therefore, its electron count decreases. Its oxidation number increases accordingly. The number of ions in solution is not a defining criterion for oxidation; ions may increase, decrease, or remain unchanged depending on the reaction context.
Step-by-Step Solution:
Apply definition: oxidation → loss of electrons.Infer consequence: electron count associated with that species decreases.Check oxidation number: it rises (not decreases) during oxidation.Recognize ion count is not a general indicator for oxidation state changes.Verification / Alternative check:Half-reaction examples: Fe^2+ → Fe^3+ + e^− shows one electron lost; oxidation number of Fe increases from +2 to +3 while electrons decrease by 1 for the species.
Why Other Options Are Wrong:
- Oxidation number decreases: opposite of what occurs in oxidation.
- Number of ions: not a universal consequence of oxidation.
- All of these: cannot be true since (b) is false.
Common Pitfalls:Equating oxidation with oxygen addition only; the electron-transfer definition is more general and applies broadly.
Final Answer:number of electrons (electron count associated with the species)