Nuclear materials: compared with metallic nuclear fuels or structural metals, ceramic nuclear materials (e.g., UO2, BeO, SiC) characteristically exhibit which property more prominently?

Difficulty: Easy

Correct Answer: Higher melting points

Explanation:


Introduction / Context:
Ceramic nuclear materials such as uranium dioxide (UO2), beryllia (BeO), alumina (Al2O3), silicon carbide (SiC), and zirconia (ZrO2) are widely used as fuels, coatings, and accident-tolerant claddings. Comparing their bulk properties with metallic nuclear materials (e.g., uranium metal, stainless steels, zirconium alloys) helps explain why reactors prefer ceramics for fuels while relying on metals for cladding and structures.


Given Data / Assumptions:

  • “Ceramic” refers to refractory, ionic/covalent compounds typically hard and brittle.
  • “Metallic nuclear materials” refers to fuel metals (U, Pu) and structural alloys (Zircaloy, austenitic steels).
  • We compare generic property trends important to reactor service.


Concept / Approach:
Ceramics usually have very high melting points and good chemical stability, making them dimensionally stable at reactor temperatures. Metals, while ductile and tough, soften at elevated temperature and often melt far below ceramic fuels. Ceramics also generally resist aqueous corrosion and radiolysis better than many metals, although they have lower thermal conductivity than most metals and are brittle.


Step-by-Step Solution:
Identify key distinguishing properties: melting point, corrosion behavior, radiation stability, thermal conductivity, and high-temperature strength.Ceramics (e.g., UO2) melt well above 2700 °C; metals used in reactor cores melt far lower (e.g., Zr ~1850 °C, steels ~1400–1500 °C, uranium metal ~1130 °C).Ceramics typically maintain stiffness at high temperature but are brittle; “low strength at high temperature” is not generically correct compared to metals that lose strength as temperature rises.Radiation: many ceramics tolerate displacement damage without catastrophic creep or swelling; “greater susceptibility” is not generally true.Corrosion: oxide ceramics are often more chemically inert than metals in water/steam; “poorer corrosion resistance” is incorrect.Thermal conductivity: most ceramics (UO2, ZrO2, Al2O3) have lower conductivity than metals; “much higher thermal conductivity” is wrong.


Verification / Alternative check:
Fuel choice illustrates the trend: UO2 is favored over uranium metal primarily for its high melting point and better dimensional/chemical stability despite its modest thermal conductivity. Accident-tolerant fuel claddings increasingly consider ceramics/ceramic composites for similar reasons.


Why Other Options Are Wrong:

  • Lower strength at high temperature: metals typically lose strength faster; ceramics retain stiffness but are brittle.
  • Greater radiation damage: many ceramics are comparatively radiation-resistant.
  • Poorer corrosion resistance: oxide ceramics resist corrosion well in many coolants.
  • Much higher thermal conductivity: opposite—metals conduct heat better.


Common Pitfalls:
Equating brittleness with low high-temperature capability; assuming the fuel must be metallic for good heat removal despite high ceramic melting points.


Final Answer:
Higher melting points

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