Natural occurrence: the proportion of heavy water (D2O) naturally present in ordinary water is closest to which percentage?
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A0.015
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B7.54
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C0.71
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D32.97
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E0.0015
Answer
Correct Answer: 0.015
Explanation
Introduction / Context:Ordinary water contains a small fraction of molecules in which deuterium replaces protium, forming heavy water (D2O) or semi-heavy water (HDO). Quantifying this natural abundance underpins heavy-water production processes and isotopic analyses in geoscience and biology.
Given Data / Assumptions:
- Natural deuterium abundance in the hydrosphere is roughly 0.015–0.016% by atoms.
- We express the order of magnitude as a simple percentage for MCQ purposes.
- Temperature/salinity variations cause only small local deviations.
Concept / Approach:The tiny natural deuterium content means heavy-water production requires energy-intensive separation (e.g., Girdler sulfide or distillation). The figure most commonly cited in introductory texts is about 0.015%, which sets expectations for feedstock enrichment effort.
Step-by-Step Solution:Recall canonical deuterium abundance ≈ 0.015–0.016%.Map this to the options; 0.015% matches closely.Choose 0.015.
Verification / Alternative check:Isotopic ratio standards (VSMOW) indicate deuterium/hydrogen ratios consistent with ~0.015% abundance, validating the chosen value.
Why Other Options Are Wrong:
- 7.54 and 32.97: Orders of magnitude too high.
- 0.71: Associated with U-235 in natural uranium, not deuterium in water.
- 0.0015: Too low by about an order of magnitude.
Common Pitfalls:Confusing U-235 abundance (0.71%) with deuterium; missing the percent versus fraction distinction.
Final Answer:0.015