Portland cement manufacture — identify the raw material blend Cement used for normal concrete construction is produced by burning a carefully proportioned mixture of which categories of natural materials?

Introduction / Context:
Ordinary Portland Cement (OPC) is manufactured by heating a precise blend of raw materials in a rotary kiln to produce clinker, which is then ground with a small amount of gypsum. Knowing the categories of raw materials helps in understanding kiln feed chemistry and performance of the final cement.

Given Data / Assumptions:

• Standard OPC manufacture (not special cements).
• Natural mineral sources are combined to reach appropriate oxides.
• Gypsum is added later for setting control.

Concept / Approach:
The kiln feed must supply the principal oxides: CaO, SiO2, Al2O3, and Fe2O3. Calcareous materials (e.g., limestone) provide CaO; argillaceous materials (clay/shale) supply Al2O3 and SiO2; siliceous components ensure adequate SiO2. In practice, a combination of calcareous, argillaceous, and siliceous materials is proportioned to meet the desired lime saturation factor and other moduli before burning to clinker.

Step-by-Step Solution:

Verification / Alternative check:
Raw mix design is routinely expressed in terms of lime saturation factor and silica/alumina ratios that depend on the correct combination of these material groups.

Why Other Options Are Wrong:

• (a), (b), (c) omit one necessary category and cannot alone achieve balanced clinker chemistry.
• (e) Incorrect because the complete list is option (d).

Common Pitfalls:
Confusing raw mix categories with later additions like gypsum; overlooking the role of minor iron-bearing materials used to adjust Fe2O3 and burnability.

Final Answer:
Siliceous, argillaceous, and calcareous materials