In catalytic reforming of naphtha to improve gasoline octane and produce reformate/aromatics, what are the typical operating pressure and temperature ranges?
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A1–5 kgf/cm2 and 200 °C
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B15–45 kgf/cm2 and 450–550 °C
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C50–75 kgf/cm2 and 600–800 °C
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D5–10 kgf/cm2 and 150–250 °C
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E25–30 kgf/cm2 and 300–350 °C
Answer
Correct Answer: 15–45 kgf/cm2 and 450–550 °C
Explanation
Introduction:Catalytic reforming converts low-octane naphtha into high-octane reformate rich in aromatics and isoparaffins, also generating hydrogen. Operating severity (temperature and pressure) directly affects octane gain, aromatics formation, and catalyst life.
Given Data / Assumptions:
- Process: Platforming/CCR or semi-regenerative reforming with Pt-based catalysts.
- Goal: representative operating windows, not extreme cases.
- Outputs: reformate octane and hydrogen co-production.
Concept / Approach:Typical reforming conditions are high temperature (about 450–520+ °C) and moderate hydrogen pressure (roughly 15–45 kgf/cm2). Lower pressure favors octane/aromatics but increases coking; CCR technology manages coke by continuous regeneration.
Step-by-Step Solution:1) Identify standard industrial ranges.2) Exclude unrealistically low T/P that would not drive dehydrogenation/cyclization.3) Select 15–45 kgf/cm2 and 450–550 °C as the representative range.
Verification / Alternative check:Process licensor data and refinery texts consistently quote 450–520 °C with 10–35 bar (approx. 10–35 kgf/cm2) for conventional/semi-regenerative units; broader 15–45 kgf/cm2 captures typical practice.
Why Other Options Are Wrong:a/d/e: Temperatures are too low for efficient reforming chemistry.c: Pressures and temperatures are excessive and not characteristic of reforming.
Common Pitfalls:Confusing reforming with hydrocracking or thermal cracking; reforming is endothermic and requires high temperature but only moderate hydrogen pressure for stability and selectivity.
Final Answer:15–45 kgf/cm2 and 450–550 °C