Feedstock for caprolactam (nylon-6 precursor): which starting material is commonly used in industry?

Difficulty: Easy

Correct Answer: Cyclohexane

Explanation:


Introduction / Context:
Caprolactam is the monomer for nylon-6. Its industrial synthesis routes typically begin with cyclohexane or related cyclohexanone/cyclohexanol intermediates.



Given Data / Assumptions:

  • Cyclohexane is oxidised to cyclohexanone/cyclohexanol (KA oil).
  • Beckmann rearrangement of cyclohexanone oxime yields caprolactam.
  • Other listed chemicals correspond to different polymer chains (e.g., DMT and ethylene glycol → PET; ethylbenzene → styrene).



Concept / Approach:
Match each option to its downstream polymer. The only one that maps to caprolactam (nylon-6) is cyclohexane via cyclohexanone/oxime chemistry.



Step-by-Step Solution:
Identify the KA-oil route to cyclohexanone.Apply Beckmann rearrangement to obtain caprolactam.Select cyclohexane as the starting material.



Verification / Alternative check:
Alternate routes exist (e.g., phenol → cyclohexanone), but the industrial chain still passes through KA-oil and oxime steps.



Why Other Options Are Wrong:
DMT + ethylene glycol → PET; ethylbenzene → styrene; ethylene glycol alone is unrelated to caprolactam.



Common Pitfalls:
Confusing nylon-6 and nylon-66 monomer routes.



Final Answer:
Cyclohexane

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