Polymethyl methacrylate (PMMA), also called Perspex or acrylic glass, is produced by bulk polymerisation of methyl methacrylate. PMMA is not a/an ______ polymer. Select the most accurate completion.
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AThermoplastic
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BThermosetting
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CLinear
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DGlass-like transparent
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EAmorphous optical-grade
Answer
Correct Answer: Thermosetting
Explanation
Introduction / Context:PMMA (acrylic glass) is widely used for glazing, lenses, and transparent housings because of its clarity and weatherability. Understanding whether PMMA behaves as a thermoplastic or thermoset informs processing options (injection molding, extrusion, thermoforming) and recyclability.
Given Data / Assumptions:
- Methyl methacrylate undergoes chain-growth (addition) polymerisation to PMMA.
- PMMA exhibits glass-like transparency and is moldable.
- Thermoplastics can be reheated and reshaped below their degradation temperature.
Concept / Approach:PMMA is a linear (though possibly lightly branched) addition polymer. It softens upon heating and can be remolded, which is characteristic of thermoplastics, not thermosets. Thermosets form infusible, three-dimensional networks that do not melt. Therefore, the statement correctly completed is that PMMA is not a thermosetting polymer.
Step-by-Step Solution:
Classify PMMA: an addition polymer of MMA.Recall that PMMA can be melted and processed repeatedly (within limits).Thermosets cannot melt; PMMA does.Hence it is not thermosetting.Verification / Alternative check:Processing guides show PMMA being injection molded and thermoformed, which are thermoplastic processes.
Why Other Options Are Wrong:
- Thermoplastic/linear/glass-like transparent/amorphous optical-grade: all describe PMMA accurately.
Common Pitfalls:Confusing “glassy” appearance with “thermoset”; glassy refers to the amorphous state above brittleness, not network chemistry.
Final Answer:Thermosetting