Polymethyl methacrylate (PMMA), also called Perspex or acrylic glass, is produced by bulk polymerisation of methyl methacrylate. PMMA is not a/an ______ polymer. Select the most accurate completion.

Difficulty: Easy

Correct Answer: Thermosetting

Explanation:


Introduction / Context:
PMMA (acrylic glass) is widely used for glazing, lenses, and transparent housings because of its clarity and weatherability. Understanding whether PMMA behaves as a thermoplastic or thermoset informs processing options (injection molding, extrusion, thermoforming) and recyclability.


Given Data / Assumptions:

  • Methyl methacrylate undergoes chain-growth (addition) polymerisation to PMMA.
  • PMMA exhibits glass-like transparency and is moldable.
  • Thermoplastics can be reheated and reshaped below their degradation temperature.


Concept / Approach:
PMMA is a linear (though possibly lightly branched) addition polymer. It softens upon heating and can be remolded, which is characteristic of thermoplastics, not thermosets. Thermosets form infusible, three-dimensional networks that do not melt. Therefore, the statement correctly completed is that PMMA is not a thermosetting polymer.


Step-by-Step Solution:

Classify PMMA: an addition polymer of MMA.Recall that PMMA can be melted and processed repeatedly (within limits).Thermosets cannot melt; PMMA does.Hence it is not thermosetting.


Verification / Alternative check:
Processing guides show PMMA being injection molded and thermoformed, which are thermoplastic processes.


Why Other Options Are Wrong:

  • Thermoplastic/linear/glass-like transparent/amorphous optical-grade: all describe PMMA accurately.


Common Pitfalls:
Confusing “glassy” appearance with “thermoset”; glassy refers to the amorphous state above brittleness, not network chemistry.


Final Answer:
Thermosetting

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