In boiler-feed-water conditioning, which unit process is used specifically to remove dissolved (soluble) silica from the water?
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ACoagulation with alum
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BPressure filtration
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CStrong-base anion exchange
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DPreheating/thermal conditioning
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EAeration and cascade towers
Answer
Correct Answer: Strong-base anion exchange
Explanation
Introduction / Context:Silica control is a critical objective in boiler-feed-water treatment because silica volatilizes and deposits on turbine blades and heat-transfer surfaces, reducing efficiency and causing maintenance issues. Unlike suspended solids, dissolved silica requires a selective removal step.
Given Data / Assumptions:
- Target constituent: dissolved (reactive) silica, not particulate silica only.
- Boiler duty may require very low silica (ppb levels) for high-pressure systems.
- Common pretreatment steps (coagulation, filtration) chiefly remove turbidity and colloids.
Concept / Approach:Dissolved silica (as monomeric silicic acid species) is effectively removed by strong-base anion (SBA) exchange resins, often in conjunction with demineralization trains (cation exchanger → degasser → anion exchanger → mixed bed). Coagulation/filtration are insufficient for dissolved silica; thermal conditioning may shift equilibria but does not reliably meet low-silica specifications.
Step-by-Step Solution:
1) Distinguish between particulate vs dissolved silica.2) Map removal technologies: particulate silica → clarification/filtration; dissolved → SBA resin.3) Select strong-base anion exchange for specific dissolved silica removal.4) Note that polishing by mixed-bed may follow to achieve ppb levels.Verification / Alternative check:Boiler water handbooks specify SBA or weak-base + strong-base sequences for silica control, with mixed-bed polishing where required.
Why Other Options Are Wrong:
Coagulation: targets colloids/suspended solids, not dissolved silica to low ppb.Pressure filtration: removes particles, not dissolved species.Preheating: may reduce carbon dioxide or assist deaeration; does not reliably remove dissolved silica.Aeration: oxidizes/strips gases; not for silica.Common Pitfalls:Confusing particulate turbidity control with dissolved silica removal; overlooking need for resin regeneration and silica leakage monitoring.
Final Answer:Strong-base anion exchange