In boiler-feed-water conditioning, which unit process is used specifically to remove dissolved (soluble) silica from the water?

Difficulty: Medium

Correct Answer: Strong-base anion exchange

Explanation:


Introduction / Context:
Silica control is a critical objective in boiler-feed-water treatment because silica volatilizes and deposits on turbine blades and heat-transfer surfaces, reducing efficiency and causing maintenance issues. Unlike suspended solids, dissolved silica requires a selective removal step.


Given Data / Assumptions:

  • Target constituent: dissolved (reactive) silica, not particulate silica only.
  • Boiler duty may require very low silica (ppb levels) for high-pressure systems.
  • Common pretreatment steps (coagulation, filtration) chiefly remove turbidity and colloids.


Concept / Approach:
Dissolved silica (as monomeric silicic acid species) is effectively removed by strong-base anion (SBA) exchange resins, often in conjunction with demineralization trains (cation exchanger → degasser → anion exchanger → mixed bed). Coagulation/filtration are insufficient for dissolved silica; thermal conditioning may shift equilibria but does not reliably meet low-silica specifications.


Step-by-Step Solution:

1) Distinguish between particulate vs dissolved silica.2) Map removal technologies: particulate silica → clarification/filtration; dissolved → SBA resin.3) Select strong-base anion exchange for specific dissolved silica removal.4) Note that polishing by mixed-bed may follow to achieve ppb levels.


Verification / Alternative check:
Boiler water handbooks specify SBA or weak-base + strong-base sequences for silica control, with mixed-bed polishing where required.


Why Other Options Are Wrong:

Coagulation: targets colloids/suspended solids, not dissolved silica to low ppb.Pressure filtration: removes particles, not dissolved species.Preheating: may reduce carbon dioxide or assist deaeration; does not reliably remove dissolved silica.Aeration: oxidizes/strips gases; not for silica.


Common Pitfalls:
Confusing particulate turbidity control with dissolved silica removal; overlooking need for resin regeneration and silica leakage monitoring.


Final Answer:
Strong-base anion exchange

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