Shear-thinning definition: In a pseudoplastic fluid relevant to fermentation broths, how does apparent viscosity change as stirrer speed (shear rate) increases?
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ARemains constant, independent of shear or time
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BChanges during mixing but fully returns to original value immediately after mixing stops (purely time-dependent)
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CIncreases with increasing stirrer speed (shear-thickening)
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DDecreases with increasing stirrer speed (shear-thinning)
Answer
Correct Answer: Decreases with increasing stirrer speed (shear-thinning)
Explanation
Introduction:Many biological fluids, including cell suspensions and polymer-rich media, are pseudoplastic. Correctly identifying shear-thinning behavior informs agitator sizing, power draw, and oxygen transfer modeling.
Given Data / Assumptions:
- Pseudoplasticity refers to rate dependence, not necessarily time dependence.
- Shear rate correlates with stirrer speed in a given geometry.
- No yield stress is described.
Concept / Approach:Pseudoplastic (shear-thinning) fluids show a decrease in apparent viscosity as shear rate increases. Microstructure (entanglements, flocs) aligns or breaks down under shear, providing less resistance to flow. This is distinct from thixotropy (time-dependent) or dilatancy (shear-thickening).
Step-by-Step Solution:Raise stirrer speed ⇒ higher shear rate in the vessel.Microstructure aligns/breaks ⇒ lower resistance to deformation.Observed effect ⇒ apparent viscosity decreases.Classify ⇒ pseudoplastic (shear-thinning).
Verification / Alternative check:Flow curves (log viscosity vs. log shear rate) show a negative slope for pseudoplastic fluids; power-law fits exhibit flow index n < 1.
Why Other Options Are Wrong:Constant viscosity: Newtonian behavior, not pseudoplastic.
Purely time-dependent recovery: thixotropy; rate dependence is not implied.
Increases with speed: dilatant (shear-thickening), opposite of pseudoplastic.
Common Pitfalls:
- Conflating rate-dependent thinning with time-dependent thinning (thixotropy).
- Assuming one measurement at a single speed reveals full rheology; multiple shear rates are needed.
Final Answer:Decreases with increasing stirrer speed (shear-thinning)