Ashwini hits the target definitely, hence required probability that atleast 2 shots hit the target is given by
Karan hits tha target and Raja not hit the target.
or
Karan does not hit the target and Raja hits the target.
or.
Karan hits the target and Raja hits the target
= 2/6 x 3/6 + 4/6 x 3/6 + 2/6 x 3/6
= 24/36 = 2/3