In chemical bonding, which of the following types of bond is generally considered the weakest in nature among those listed?

Difficulty: Easy

Correct Answer: Hydrogen bond

Explanation:


Introduction / Context:
This question checks your understanding of the relative strengths of different types of chemical bonds and interactions. In chemistry, we often distinguish between strong intramolecular covalent or ionic bonds that hold atoms together in a molecule or crystal, and weaker intermolecular forces such as hydrogen bonds and van der Waals forces that act between molecules. Recognising which interactions are weaker helps explain properties like boiling points and solubilities.


Given Data / Assumptions:

  • The options include single, double and triple covalent bonds, a hydrogen bond, and an ionic bond.
  • We are asked which type is generally the weakest in nature among the listed choices.
  • Assume typical bond strengths in covalent molecules and common ionic solids.


Concept / Approach:
Single, double and triple covalent bonds are strong intramolecular bonds formed by sharing electrons between atoms. In general, triple bonds are strongest, double bonds are intermediate, and single bonds are somewhat weaker but still much stronger than typical intermolecular interactions. Ionic bonds between oppositely charged ions in a crystal lattice are also strong. Hydrogen bonds, although stronger than many other intermolecular forces, are still weaker than covalent and ionic bonds. Therefore, among the given choices, hydrogen bonds are the weakest.


Step-by-Step Solution:

Step 1: Consider single, double and triple covalent bonds. These are bonds within molecules, and their bond energies are usually high, especially for double and triple bonds. Step 2: Remember that triple bonds such as in nitrogen molecules are usually the strongest covalent bonds, followed by double bonds and then single bonds. Step 3: Ionic bonds involve strong electrostatic attraction between positively and negatively charged ions in solids like sodium chloride and are also high energy bonds. Step 4: Hydrogen bonds arise when a hydrogen atom bonded to a very electronegative atom such as oxygen, nitrogen or fluorine is attracted to another electronegative atom in a neighbouring molecule. Step 5: Hydrogen bonds are weaker than covalent and ionic bonds, although they are stronger than many other intermolecular forces. This makes hydrogen bond the weakest among the listed options.


Verification / Alternative check:
Typical bond energy tables show covalent bond energies in the range of hundreds of kilojoules per mole, for example C–C or O–H bonds. Ionic lattice energies are also very high. In contrast, hydrogen bond energies are usually much smaller, often tens of kilojoules per mole. This large difference in bond energy supports the idea that hydrogen bonds are weaker than true covalent or ionic bonds. Many physical properties of water, DNA and proteins show the important but relatively weak nature of hydrogen bonding compared to covalent bonding in their backbones.


Why Other Options Are Wrong:

  • Single covalent bond: Although weaker than double and triple covalent bonds, it is still much stronger than hydrogen bonds.
  • Double covalent bond: Stronger than a single bond and far stronger than hydrogen bonds.
  • Triple covalent bond: Typically the strongest among covalent bonds, not the weakest.
  • Ionic bond: Electrostatic attraction holds ions strongly in a lattice, giving high melting points and hardness, so it is not the weakest type listed.


Common Pitfalls:
Some learners mix up the idea of the number of bonds with their strength and may think that single bonds must be very weak. While single covalent bonds are weaker than double or triple bonds, they are still much stronger than hydrogen bonds. Another common confusion is to treat hydrogen bonds as if they were a kind of full covalent bond. Remember that hydrogen bonds are intermolecular attractions, weaker than the true bonds within molecules, even though they have a big effect on physical properties like boiling point and viscosity.


Final Answer:
The weakest type of bond among the options given is the Hydrogen bond.

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