Storage practice for volatile liquids (e.g., naphtha): which roof configuration is commonly used on cylindrical tanks to minimize vapor losses and reduce emissions?

Difficulty: Easy

Correct Answer: Floating

Explanation:


Introduction / Context:
Volatile hydrocarbons like naphtha generate significant vapor above the liquid surface. Managing these vapors is essential to reduce product losses and atmospheric emissions. Tank roof design is therefore a key environmental and safety control in storage terminals and refineries.



Given Data / Assumptions:

  • Cylindrical atmospheric storage tank.
  • Stored liquid is volatile (high vapor pressure).
  • Goal is to minimize breathing and working losses from vapor space.


Concept / Approach:
A floating roof (either external or internal) rests directly on the liquid surface, keeping vapor space volume minimal across operating levels. This reduces vapor-generation area and limits evaporation and emissions. By contrast, fixed or conical/flat roofs leave a vapor space whose composition changes with temperature and liquid level, causing greater breathing losses.



Step-by-Step Solution:

Identify the dominant loss mechanisms: breathing and working losses.Select a roof type that tracks the liquid level to shrink vapor space.Floating roof tanks best satisfy these aims for volatile liquids like naphtha.


Verification / Alternative check:
Industry guidance and emission inventories consistently show lower losses for floating roof tanks compared to fixed roof tanks storing high-volatility products.



Why Other Options Are Wrong:

  • Conical, flat, or generic fixed roofs maintain a headspace, increasing vapor losses unless combined with internal floating covers and vapor control systems.


Common Pitfalls:
Ignoring rim-seal integrity and deck fittings (sources of residual emissions); overlooking wind effects on external floating roofs; not considering internal floating roofs under fixed covers in strict-weather locations.



Final Answer:
Floating

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