Vapor terminology: A vapor whose partial pressure is less than its saturation (equilibrium) vapor pressure at the same temperature is called a __________ vapor.
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Asaturated
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Bsupersaturated
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Csuperheated
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Dnone of these
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Ewet
Answer
Correct Answer: superheated
Explanation
Introduction / Context:Precise terminology in phase equilibria helps avoid confusion in design of condensers, evaporators, and dryers. The relation between a vapor’s actual partial pressure and the saturation vapor pressure at the same temperature classifies the state as saturated, superheated, or supersaturated.
Given Data / Assumptions:
- Single-component vapor or a vapor in a gas mixture at temperature T.
- Saturation pressure p_sat(T) is the equilibrium vapor pressure at T.
- Partial pressure p_v of the vapor is known and p_v < p_sat(T).
Concept / Approach:When p_v = p_sat(T), the vapor is saturated and in equilibrium with its liquid. If p_v < p_sat(T) at the same temperature, the vapor has “excess temperature” relative to its saturation state: it is superheated. Supersaturated refers to a metastable state where p_v > p_sat(T) (or, equivalently, where relative humidity > 100% in gas–vapor mixtures), which is unstable and tends to condense upon nucleation.
Step-by-Step Solution:
Compare actual partial pressure p_v to p_sat(T).Given p_v < p_sat(T).Therefore, the vapor is superheated.Select “superheated.”Verification / Alternative check:On T–s or P–h diagrams, states to the right of the saturated vapor line at the same pressure are superheated; equivalently, at constant T, a vapor with lower pressure than saturation is superheated.
Why Other Options Are Wrong:
- Saturated: requires p_v = p_sat(T).
- Supersaturated: implies p_v > p_sat(T), the opposite case.
- Wet: indicates a mixture containing liquid droplets, not appropriate here.
- None of these: incorrect; the standard term is superheated.
Common Pitfalls:Confusing “supersaturated” with “superheated”; supersaturation is an overpressure (or overconcentration) state prone to condensation, whereas superheating is an underpressure state relative to saturation.
Final Answer:superheated