Vapor terminology: A vapor whose partial pressure is less than its saturation (equilibrium) vapor pressure at the same temperature is called a __________ vapor.

Difficulty: Easy

Correct Answer: superheated

Explanation:


Introduction / Context:
Precise terminology in phase equilibria helps avoid confusion in design of condensers, evaporators, and dryers. The relation between a vapor’s actual partial pressure and the saturation vapor pressure at the same temperature classifies the state as saturated, superheated, or supersaturated.


Given Data / Assumptions:

  • Single-component vapor or a vapor in a gas mixture at temperature T.
  • Saturation pressure p_sat(T) is the equilibrium vapor pressure at T.
  • Partial pressure p_v of the vapor is known and p_v < p_sat(T).


Concept / Approach:
When p_v = p_sat(T), the vapor is saturated and in equilibrium with its liquid. If p_v < p_sat(T) at the same temperature, the vapor has “excess temperature” relative to its saturation state: it is superheated. Supersaturated refers to a metastable state where p_v > p_sat(T) (or, equivalently, where relative humidity > 100% in gas–vapor mixtures), which is unstable and tends to condense upon nucleation.


Step-by-Step Solution:

Compare actual partial pressure p_v to p_sat(T).Given p_v < p_sat(T).Therefore, the vapor is superheated.Select “superheated.”


Verification / Alternative check:
On T–s or P–h diagrams, states to the right of the saturated vapor line at the same pressure are superheated; equivalently, at constant T, a vapor with lower pressure than saturation is superheated.


Why Other Options Are Wrong:

  • Saturated: requires p_v = p_sat(T).
  • Supersaturated: implies p_v > p_sat(T), the opposite case.
  • Wet: indicates a mixture containing liquid droplets, not appropriate here.
  • None of these: incorrect; the standard term is superheated.


Common Pitfalls:
Confusing “supersaturated” with “superheated”; supersaturation is an overpressure (or overconcentration) state prone to condensation, whereas superheating is an underpressure state relative to saturation.


Final Answer:
superheated

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