Fuel sweetening in refining: In petroleum product treatment, “sweetening” primarily refers to the removal or conversion of which species?

Difficulty: Easy

Correct Answer: Sulphur and its odorous compounds (e.g., mercaptans)

Explanation:


Introduction:
“Sweet” petroleum products are low in sulphur and mercaptans, with reduced odour and corrosivity. Processes include mercaptan oxidation (Merox) or hydrotreating to convert/remove sulphur species.


Given Data / Assumptions:

  • Scope: finished product treating.
  • Goal: odour reduction, improved stability/corrosion performance.


Concept / Approach:
Sweetening targets sulphur-bearing compounds. Merox oxidises mercaptans to disulfides (less odorous), while hydrotreating removes sulphur as H2S. Hence, “sweetening” refers to sulphur compound removal/conversion.


Step-by-Step Solution:

Identify key contaminants: mercaptans/sulphur species.Match to product “sweetness.”Select the option explicitly naming sulphur/mercaptans.


Verification / Alternative check:
Product specifications (e.g., mercaptan sulphur limits) define “sweet.”


Why Other Options Are Wrong:

  • Water: Removed by drying, not sweetening.
  • Organic particulates/wax/asphaltenes: Other treatments handle these.


Common Pitfalls:
Equating dehydration or filtration with sweetening.


Final Answer:
Sulphur and its odorous compounds (e.g., mercaptans)

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