Refrigerant property of ammonia: The __________ point of ammonia (NH₃) at standard pressure is −77.7°C.

Difficulty: Easy

Correct Answer: freezing (melting)

Explanation:


Introduction / Context:
Ammonia (R-717) is a widely used refrigerant in industrial systems. Knowing its key thermophysical properties—boiling, freezing, and critical points—is essential for safe and reliable design.



Given Data / Assumptions:

  • Standard atmospheric pressure conditions.
  • Ammonia’s normal boiling point is approximately −33.3°C.
  • The stated temperature is −77.7°C.


Concept / Approach:
Compare the given temperature with known characteristic temperatures. Because −77.7°C is far below the normal boiling point, it aligns with the freezing (melting) point of ammonia, the temperature at which liquid ammonia solidifies at 1 atm.



Step-by-Step Solution:

Recall key points: T_boil,1atm ≈ −33.3°C; T_freeze ≈ −77.7°C; T_critical ≈ 132.4°C (critical temperature).Match the given −77.7°C to these known values.Conclude that −77.7°C corresponds to the freezing (melting) point.Therefore the blank should be “freezing (melting)”.


Verification / Alternative check:
Consult standard property tables for R-717 to confirm the numerical values; industrial design texts list these constants consistently.



Why Other Options Are Wrong:

  • Boiling point is −33.3°C at 1 atm, not −77.7°C.
  • Critical point temperature is above 100°C, not negative.
  • Dew point refers to saturation temperature at a given pressure for vapour mixtures, not a fixed constant for a pure substance at 1 atm.


Common Pitfalls:
Confusing boiling and freezing points for substances with negative values; always cross-reference known constants.



Final Answer:
freezing (melting)

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