Difficulty: Easy
Correct Answer: Fluorine
Explanation:
Introduction / Context:
This general chemistry question tests knowledge of electronegativity, a key periodic property. Electronegativity measures the tendency of an atom in a molecule to attract shared electrons towards itself. Knowing which element is most electronegative is important for predicting bond polarity, molecular structure and reactivity patterns.
Given Data / Assumptions:
Concept / Approach:
On the Pauling scale, fluorine has the highest electronegativity of all elements, with a value around 4.0. Oxygen is also very electronegative, but its value is lower than that of fluorine. Among the halogens, electronegativity decreases as we go down the group from fluorine to chlorine to bromine to iodine. Thus, in any list that includes fluorine and oxygen along with heavier halogens, fluorine will be the most electronegative element.
Step-by-Step Solution:
1) Recall the general trend: electronegativity increases across a period from left to right and decreases down a group in the periodic table.2) In the halogen group (group 17), the order of electronegativity from highest to lowest is: fluorine > chlorine > bromine > iodine.3) Oxygen is very electronegative and lies to the right in period 2, but it still has a lower electronegativity than fluorine.4) Compare fluorine and oxygen directly: fluorine is at the extreme top right (excluding noble gases), so it is the most electronegative element in the entire periodic table.5) Bromine and iodine are below fluorine and chlorine in the same group, so their electronegativities are lower than that of fluorine.6) Therefore, the most electronegative element among fluorine, bromine, iodine and oxygen is fluorine.
Verification / Alternative check:
Pauling electronegativity values are approximately: fluorine 4.0, oxygen 3.5, chlorine 3.0, bromine 2.8 and iodine 2.5. These numerical values confirm the qualitative trend described. Fluorine value is the highest listed, not only among the given options but among all elements. This is why bonds such as H–F are very polar and why fluorine is an extremely reactive non metal.
Why Other Options Are Wrong:
Bromine: Its electronegativity is lower than that of fluorine and chlorine because it is further down the group.Iodine: Being even lower in the halogen group, iodine has an electronegativity significantly less than fluorine.Oxygen: Very electronegative and second only to fluorine in many tables, but it is still less electronegative than fluorine.Chlorine: Not in the original list but often present as a distractor; it is less electronegative than fluorine.
Common Pitfalls:
Students sometimes confuse high reactivity with high electronegativity and may mistakenly think oxygen is the most electronegative because of its role in combustion and oxidation. A simple way to avoid this error is to remember that fluorine occupies the topmost right position among the elements that form stable compounds and is explicitly identified in textbooks as the most electronegative element. Whenever fluorine appears as an option in such questions, it is almost always the correct answer for highest electronegativity.
Final Answer:
The most electronegative element among the options is fluorine.
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