Kelvin–Planck statement of the second law: Is it possible to construct a cyclic heat engine whose sole effect is to convert all absorbed heat into work?

Difficulty: Easy

Correct Answer: impossible

Explanation:


Introduction / Context:
This question targets the Kelvin–Planck statement of the second law of thermodynamics, which places a fundamental limit on the performance of heat engines operating in cycles.


Given Data / Assumptions:

  • A cyclic device exchanging heat and work with surroundings.
  • Sole purpose: convert heat into work with no other effect.
  • No allowance for additional reservoirs or changes elsewhere.


Concept / Approach:
The Kelvin–Planck statement asserts that it is impossible to devise a cyclic engine that converts all heat received from a single thermal reservoir entirely into work. Some heat must be rejected to a lower-temperature reservoir. Thus, 100% conversion in a cycle violates the second law.


Step-by-Step Solution:

Define a cyclic engine with heat input Q_in.If W_out = Q_in and Q_out = 0, efficiency would be 100%.Second law forbids this for any real or ideal cyclic device.


Verification / Alternative check:
Carnot's theorem: Even the ideal reversible engine (Carnot) has efficiency η = 1 − T_c/T_h < 1 for finite temperatures, requiring Q_out > 0 unless T_c = 0 K (unattainable).


Why Other Options Are Wrong:

  • Possible / possible with an ideal gas / possible at absolute zero: Each contradicts the second law or invokes unattainable conditions.


Common Pitfalls:
Confusing one-shot energy conversion (non-cyclic) with cyclic operation; misinterpreting the role of multiple reservoirs.


Final Answer:
impossible

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