Kinetic Theory — Temperature Dependence of Molecular Speeds According to the kinetic theory of gases, how does the average molecular speed change with increasing temperature (for a given gas)?

Difficulty: Easy

Correct Answer: increases

Explanation:


Introduction / Context:
Kinetic theory links macroscopic temperature to microscopic molecular motion. Understanding this relationship is essential for diffusion, viscosity, and speed of sound calculations in gases.


Given Data / Assumptions:

  • Ideal gas approximation.
  • Molecular mass constant for the gas.
  • Temperature measured on an absolute scale (kelvin).


Concept / Approach:
The root-mean-square (rms) speed is given by c_rms = sqrt(3 * R_specific * T) = sqrt(3 * k_B * T / m). As temperature T increases, c_rms increases with the square root of T for a fixed molecular mass m, meaning molecules move faster on average at higher temperatures.


Step-by-Step Solution:
Write c_rms = sqrt(3 * R_specific * T).At constant gas species (R_specific fixed), c_rms ∝ sqrt(T).Therefore, as T increases, average molecular speed increases.


Verification / Alternative check:
Maxwell–Boltzmann distributions broaden and shift to higher speeds with temperature, consistent with the square-root dependence of characteristic speeds (most probable, mean, rms) on T.


Why Other Options Are Wrong:
“Remains constant” would require no temperature effect; “decreases” contradicts kinetic theory relations.


Common Pitfalls:
Confusing effects of changing gas species (m changes) with changing temperature for a fixed gas; mixing Celsius changes with absolute Kelvin changes in proportional formulas.


Final Answer:
increases

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