Drinking water aesthetics and staining: What is the common consequence in households when iron and manganese are present in distributed water at elevated levels (above aesthetic limits)?

Difficulty: Easy

Correct Answer: Discoloration and staining of bathroom fixtures and laundry

Explanation:


Introduction / Context:
Iron and manganese frequently occur in groundwater and, when delivered to consumers without adequate treatment, lead to aesthetic and operational issues. While not typically acute toxicants at low concentrations, their presence above secondary standards creates nuisance problems that utilities strive to prevent.


Given Data / Assumptions:

  • The question focuses on practical household consequences.
  • “Elevated levels” implies concentrations above aesthetic guidelines (e.g., iron > 0.3 mg/L, manganese > 0.05 mg/L).
  • Water is otherwise potable with routine disinfection.


Concept / Approach:
When iron and manganese oxidize, they form colored particulates (reddish-brown iron oxides, black manganese oxides) that deposit on porcelain fixtures, tiles, and laundry, causing conspicuous staining. They also impart metallic taste and can promote biofouling, but the most visible symptom is discoloration and staining.


Step-by-Step Solution:
Identify metal species: Fe2+/Mn2+ oxidize to insoluble oxides/hydroxides.Relate oxidation products to appearance: rust-colored or black deposits.Select the outcome most consistent with household complaints: staining/discoloration.


Verification / Alternative check:
Customer service records at utilities commonly register “brown water” and staining events tied to iron and manganese breakthrough or distribution system disturbances.


Why Other Options Are Wrong:
Reduction in dissolved oxygen content: DO is a bulk water parameter, not a direct consumer-visible effect from trace Fe/Mn.Temporary hardness: caused by bicarbonates of calcium and magnesium, not Fe/Mn specifically.Acute microbial contamination: unrelated to Fe/Mn presence per se.


Common Pitfalls:
Equating any mineral issue with hardness; overlooking the distinct aesthetic signatures of iron (reddish) and manganese (black/gray) deposits.


Final Answer:
Discoloration and staining of bathroom fixtures and laundry

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