Toxic gas safety: above what airborne concentration of hydrogen sulphide (H2S) is there an acute danger to human life based on typical industrial hygiene references?
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A50 ppm
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B100 ppm
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C300 ppm
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D700 ppm
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E1500 ppm
Answer
Correct Answer: 700 ppm
Explanation
Introduction / Context:Hydrogen sulphide (H2S) is a rapidly acting toxic gas found in sewers, petroleum refining, tanneries, and pulp mills. Its toxicity rises steeply with concentration, making accurate hazard thresholds essential for confined space safety.
Given Data / Assumptions:
- We seek a threshold above which acute danger to life exists.
- Conventional safety training emphasizes rapidly fatal outcomes at very high levels.
- Context: emergency and confined-space awareness.
Concept / Approach:At tens of ppm, H2S causes eye and respiratory irritation; at hundreds of ppm, olfactory paralysis occurs, removing the warning odor; above several hundred ppm, collapse, respiratory arrest, and death can occur quickly. Many engineering exam references cite 700 ppm as an acute life-threatening level.
Step-by-Step Solution:
1) Compare candidate values with known toxicodynamics. 2) Recognize that life-threatening risk accelerates in the high-hundreds ppm. 3) Select 700 ppm as the conventional acute danger threshold in many reference tables.Verification / Alternative check:Confined-space rescue protocols treat several-hundred-ppm H2S as immediately dangerous to life and health, requiring supplied-air protection and ventilation before entry.
Why Other Options Are Wrong:
- 50 ppm: hazardous, but typically below acute life-threatening guidance levels.
- 100 ppm: severe irritation; still below the widely cited acute danger value.
- 300 ppm: extremely dangerous; some sources mark critical risk here, but 700 ppm is the value many exam keys use for acute danger to life.
- 1500 ppm: lethal zone, but the question asks for the onset threshold.
Common Pitfalls:Relying on smell as a warning (olfactory fatigue occurs); underestimating rapid onset of respiratory collapse at high concentrations.
Final Answer:700 ppm