Glyptal-type alkyd resins (phthalic anhydride + glycerol): which of the following is NOT a typical application?
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ASurface coating of automobiles and aircraft
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BFibre making (as a fibre-forming polymer)
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CPlasticiser for PVC and nitrocellulose systems
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DFilm-forming materials in paints
Answer
Correct Answer: Fibre making (as a fibre-forming polymer)
Explanation
Introduction / Context:Glyptal is a classic alkyd resin widely used in coatings. While alkyds can modify flexibility and adhesion in films (and can be blended with plasticisers), they are not used as primary fibre-forming polymers like PET, nylon, or acrylics.
Given Data / Assumptions:
- Composition: phthalic anhydride + glycerol (plus fatty acids/oils).
- Applications: enamels, varnishes, primers, and as modifiers/plasticisers in coatings.
- Industrial fibre spinning demands polymers tailored for melt/solution spinning and drawing.
Concept / Approach:Coatings require film formation and adhesion; alkyds excel as binders and film-formers. Fibre making requires high-molecular-weight polymers with melt stability and crystallisation behavior compatible with spinning—criteria alkyds do not satisfy.
Step-by-Step Solution:Map each option to known alkyd uses.Identify the outlier: fibre making.Select 'Fibre making (as a fibre-forming polymer)' as not typical.
Verification / Alternative check:Standards and product literature list alkyds as binders; there is no commercial fibre segment based on alkyd resins.
Why Other Options Are Wrong:Automotive/aircraft finishes, plasticiser roles in coatings, and film-forming binders are all legitimate alkyd applications.
Common Pitfalls:Interpreting 'plasticiser' as a standalone commodity; here, alkyds act in concert with or as part of film systems to impart flexibility and adhesion.
Final Answer:Fibre making (as a fibre-forming polymer)