Which bond has the greatest ionic character?

Ionic character depends on the electronegativity difference between the bonding elements. The greatest the elctronegativity diffference the greatest the ionic character.

Here in the given options, H-F has has the greatest ionic character. The electronegativity of Hydrogen is 2.1 and that of Fluorine is 4. Now the electronegativity difference is 4 - 2.1 = 1.9.