Octane number interpretation for SI fuels A petrol fuel with an octane rating of 75 has the same knocking tendency as which reference mixture by volume in the CFR test engine?
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A75% iso-octane and 25% n-heptane
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B75% n-heptane and 25% iso-octane
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C75% petrol and 25% diesel
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D75% diesel and 25% petrol
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E50% toluene and 50% ethanol
Answer
Correct Answer: 75% iso-octane and 25% n-heptane
Explanation
Introduction / Context:The octane scale for spark-ignition fuels is defined using two primary reference fuels: iso-octane, which resists knock well, and n-heptane, which knocks readily. The octane number quantifies a fuel’s knock resistance by equating it to a blend of these two references.
Given Data / Assumptions:
- Octane number of the test fuel is 75.
- Reference fuels: iso-octane (100) and n-heptane (0).
- Mixtures are expressed in percent by volume for the CFR test engine comparison.
Concept / Approach:An octane rating of 75 indicates the fuel behaves, in terms of knock tendency, like a blend containing 75% iso-octane and 25% n-heptane under standard test conditions. That is the operational definition of the research octane number scale.
Step-by-Step Solution:Map rating to blend: Octane 75 → 75 parts iso-octane + 25 parts n-heptane (by volume).Exclude distractors that swap the percentages or replace the references with unrelated fuels.Select the mixture that matches the definition.
Verification / Alternative check:Standard fuel testing protocols (RON/MON) rely on CFR engine comparisons to these defined blends.
Why Other Options Are Wrong:
- Swapped percentages invert the rating (would imply Octane 25).
- Petrol–diesel mixtures are not reference pairs for octane testing.
- Aromatic or alcohol mixtures may alter knock resistance but are not the scale’s endpoints.
Common Pitfalls:Confusing octane number (knock resistance) with calorific value or flash point; they are independent properties.
Final Answer:75% iso-octane and 25% n-heptane