Electrochemistry of batteries: which feature best characterizes a secondary cell compared to a primary cell used in everyday electronics?

Difficulty: Easy

Correct Answer: rechargeability

Explanation:


Introduction / Context:
Cells are broadly divided into primary (single-use) and secondary (rechargeable). Understanding this distinction guides selection for portable electronics, power tools, and energy storage systems.



Given Data / Assumptions:

  • Primary cells (e.g., zinc–carbon, alkaline) are designed for one discharge cycle.
  • Secondary cells (e.g., Li-ion, NiMH, lead–acid) support repeated charge–discharge cycles.
  • Form-factor (dry vs wet) is not definitive of primary vs secondary.


Concept / Approach:
Rechargeability is the defining trait of secondary cells. Their electrode reactions are designed to be chemically reversible within specified limits, allowing energy to be stored and released multiple times with acceptable capacity retention and safety.



Step-by-Step Solution:
Identify the hallmark: electrochemical reversibility → rechargeability.Contrast with primary cells: reactions proceed largely irreversibly → practical single use.Therefore, the correct distinguishing characteristic is rechargeability.


Verification / Alternative check:
Everyday examples: smartphones (Li-ion secondary), disposable AA alkaline (primary). Product labels and charger compatibility affirm the distinction.



Why Other Options Are Wrong:
“Not rechargeable”: defines primary cells, not secondary.
“Dry cell” or “non-liquid”: refer to electrolyte form, which can apply to both primary and secondary technologies.



Common Pitfalls:
Assuming a sealed “dry” battery must be non-rechargeable; many sealed secondary chemistries exist.



Final Answer:
rechargeability

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