4. A rigid vessel containing three moles of nitrogen gas at 30°C is heated to 250°C. Assume the average capacities of nitrogen to be Cp = 29.1 J/mole.°C and, Cv = 20.8 J/mole.°C. The heat required, neglecting the heat capacity of the vessel, is
5. According to Raoult's law, "The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component." Raoult's law is not applicable under the following assumption/condition.
Options
A. No component is concentrated at the surface of the solution.
B. The component molecules are non polar and are of almost equal size.
C. In the formation of solution, chemical combination/molecular association between unlike molecules takes place.
D. The attractive forces between like and unlike molecules are almost equal.
Correct Answer: In the formation of solution, chemical combination/molecular association between unlike molecules takes place.
6. Simultaneous doubling of the absolute temperature of a gas and reduction of its pressure to half, will result in __________ in the volume of the gas.