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Home Chemical Engineering Stoichiometry Comments

  • Question
  • According to Raoult's law, "The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component." Raoult's law is not applicable under the following assumption/condition.


  • Options
  • A. No component is concentrated at the surface of the solution.
  • B. The component molecules are non polar and are of almost equal size.
  • C. In the formation of solution, chemical combination/molecular association between unlike molecules takes place.
  • D. The attractive forces between like and unlike molecules are almost equal.

  • Correct Answer
  • In the formation of solution, chemical combination/molecular association between unlike molecules takes place. 


  • Stoichiometry problems


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    • 1. Pick out the wrong statement.

    • Options
    • A. One kg-mole of an ideal gas occupies 22.4 m3 at N.T.P.
    • B. One lb-mole of an ideal gas occupies 359 ft3 at N.T.P.
    • C. One gm-mole of an ideal gas occupies 22.4 litres (i.e., 22400 c.c) at N.T.P.
    • D. Density of dry air at N.T.P. is 1 gm/litre.
    • Discuss
    • 2. pH value of an alkaline solution is

    • Options
    • A. 7
    • B. > 7
    • C. < 7
    • D. constant over a wide range
    • Discuss
    • 3. Colligative properties of a dilute solution are those, which depend entirely upon the

    • Options
    • A. chemical composition of the solute.
    • B. constitution of the solute.
    • C. number of solute molecules contained in a given volume of the solvent.
    • D. none of these.
    • Discuss
    • 4. An oxidation process is accompanied by decrease in the

    • Options
    • A. number of electrons.
    • B. oxidation number.
    • C. number of ions.
    • D. all (a), (b) & (c).
    • Discuss
    • 5. 1 Pascal (unit of pressure) is equal to __________ N/m2.

    • Options
    • A. 10
    • B. 1
    • C. 0.1
    • D. 1000
    • Discuss
    • 6. A rigid vessel containing three moles of nitrogen gas at 30°C is heated to 250°C. Assume the average capacities of nitrogen to be Cp = 29.1 J/mole.°C and, Cv = 20.8 J/mole.°C. The heat required, neglecting the heat capacity of the vessel, is

    • Options
    • A. 13728 J
    • B. 19206 J
    • C. 4576 J
    • D. 12712 J
    • Discuss
    • 7. The hydroxyl ion (OH-) concentration in a solution having pH value 3 will be

    • Options
    • A. 10-11
    • B. 10-10
    • C. 10-3
    • D. 10-4
    • Discuss
    • 8. Pick out the wrong conversion formula for the conversion of weight units :

    • Options
    • A. 1 tonne = 1000 kg = 22.046 lbs
    • B. 1 U.S. ton = 907 kg = 0.907 tonne = 0.893 ton
    • C. 1 ton = 2240 lbs = 1016 kg = 1.016 tonnes = 1.12 U.S. tons
    • D. none of these
    • Discuss
    • 9. The net heat evolved or absorbed in a chemical process, i.e. total change in the enthalpy of the system is independent of the

    • Options
    • A. temperature & pressure.
    • B. number of intermediate chemical reactions involved.
    • C. state of aggregation & the state of combination at the beginning & the end of the reaction.
    • D. none of these.
    • Discuss
    • 10. The osmotic pressure of a solution increases, if its __________ is decreased.

    • Options
    • A. volume
    • B. solute concentration
    • C. temperature
    • D. none of these
    • Discuss


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