Cyanide or cyanogenic compounds are historically found in which of the following materials or foods, with one option being the exception?

Difficulty: Medium

Correct Answer: Teflon non stick coating

Explanation:


Introduction / Context:
Cyanide is a highly toxic chemical that can interfere with cellular respiration. It has a fearsome reputation in history and popular culture, but it also occurs naturally in some plant seeds as cyanogenic compounds. General science and safety education often highlight which common materials or foods may contain cyanide and which do not. This question asks students to identify the exception among several items associated with cyanide related discussions.


Given Data / Assumptions:
- The focus is on cyanide or cyanogenic compounds historically found in certain substances.
- Options include Teflon non stick coating, cherry seeds, apricot seeds, and an all of the above option.
- We assume typical household exposure and natural plant chemistry.
- The question asks which one is the exception and does not normally contain cyanide or cyanogenic compounds.


Concept / Approach:
Many stone fruit seeds, such as those of cherries, apricots, peaches, and almonds, contain compounds known as cyanogenic glycosides. When these compounds are broken down, they can release hydrogen cyanide. Therefore, cherry seeds and apricot seeds can potentially release small amounts of cyanide if crushed and ingested in large quantities. In contrast, Teflon is the trade name for polytetrafluoroethylene, a fluoropolymer used as a non stick coating on cookware. Teflon does not contain cyanide; its chemical structure is based on carbon and fluorine atoms. While Teflon can degrade and release fumes at very high temperatures, this is a different issue and does not involve cyanide. Thus, Teflon is the exception among the listed items.


Step-by-Step Solution:
Step 1: Recall that many fruit kernels of the cherry and apricot family may contain cyanogenic glycosides that can release cyanide. Step 2: Recognise that people are sometimes warned not to eat large amounts of these seeds due to potential cyanide release. Step 3: Understand that Teflon non stick coating is a synthetic polymer not related to cyanogenic plant compounds. Step 4: Evaluate the option all of the above and see that it would only be correct if every listed item contained cyanide, which is not true for Teflon. Step 5: Select Teflon non stick coating as the exception that does not historically contain cyanide.


Verification / Alternative check:
Chemistry and toxicology references confirm that cyanogenic glycosides such as amygdalin occur in seeds of apricots, cherries, and bitter almonds. These compounds can release hydrogen cyanide when metabolised. On the other hand, Teflon is composed of repeated CF2 units and is not a cyanide compound. Concerns about Teflon focus on polymer fumes at high temperatures, not cyanide. Therefore, the natural plant seeds are associated with cyanide, while Teflon is not, verifying that Teflon is the correct exception.


Why Other Options Are Wrong:
- Cherry seeds and kernels can contain cyanogenic glycosides and are known in toxicology as potential sources of cyanide if ingested in large amounts.
- Apricot seeds and kernels are also associated with cyanogenic compounds and have been linked with cyanide poisoning in some reported cases.
- All of the above is incorrect because Teflon does not contain cyanide, so not every listed option is a cyanide source.


Common Pitfalls:
Some learners may not know about cyanide in fruit seeds and might incorrectly assume that synthetic chemicals like Teflon must be more dangerous. Others may be confused by media reports about non stick cookware safety and believe that any negative news must involve cyanide. It is important to distinguish between different types of chemical risks. Natural does not always mean harmless, and synthetic does not always mean cyanide related. Understanding that cyanide in this context is linked to certain plant seeds helps identify Teflon as the exception in the list.


Final Answer:
The exception that does not historically contain cyanide is Teflon non stick coating.

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