Process instrumentation — thermal conductivity principle Which instrument classically operates on the principle of measuring thermal conductivity differences of gases?
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ACO2 analyser (katharometer type)
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BPolarimeter
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CSpectrometer
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DChromatograph
Answer
Correct Answer: CO2 analyser (katharometer type)
Explanation
Introduction / Context:Industrial gas analysis can use a variety of physical principles. Thermal conductivity measurement (katharometry) is a simple, robust method for distinguishing gases based on their ability to conduct heat.
Given Data / Assumptions:
- A katharometer uses heated elements whose temperature (and resistance) changes with the thermal conductivity of the surrounding gas.
- CO2 is often measured against a reference gas with known conductivity.
Concept / Approach:Gases have characteristic thermal conductivities. By comparing the rate of heat loss from a heated filament in the sample versus a reference cell, concentration of components like CO2 can be inferred. While modern CO2 analyzers may also use infrared absorption, the classical thermal conductivity analyzer remains a recognized category.
Step-by-Step Solution:Identify which option aligns with thermal conductivity → katharometer-style CO2 analyzer.Eliminate instruments based on optical rotation (polarimeter), spectral dispersion (spectrometer), and separation platforms (chromatograph).
Verification / Alternative check:Gas chromatography detectors include thermal conductivity detectors (TCD), but the instrument itself is a chromatographic system; here the standalone analyzer is more directly tied to the principle.
Why Other Options Are Wrong:
- Polarimeter: measures optical rotation in liquids, not gas conductivity.
- Spectrometer: optical spectra, not thermal conductivity.
- Chromatograph: separation device; only the TCD detector uses the principle, not the whole instrument by itself.
Common Pitfalls:
- Assuming all CO2 analyzers are IR; many are, but katharometers are a valid classical type.
Final Answer:CO2 analyser (katharometer type)