Measurement units — The standard redox potential of a substance under biochemical standard conditions (E°') is expressed in which unit?
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AMilliampere (mA)
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BVolt (V)
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CUnitless (no units)
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DOhm (Ω)
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EJoule (J)
Answer
Correct Answer: Volt (V)
Explanation
Introduction / Context:Redox potentials quantify the tendency of a chemical species to be reduced or oxidized and are essential for predicting electron flow and calculating free-energy changes in bioenergetics. Correct units ensure proper interpretation and use in equations that relate E°' to ΔG°'.
Given Data / Assumptions:
- E°' is an electrical potential difference measured relative to a reference electrode at pH 7.
- Potential relates to energy per unit charge.
- ΔG°' = −n * F * ΔE°' (n = number of electrons; F = Faraday constant).
Concept / Approach:Because E°' is an electrical potential, its SI unit is the volt (V). Current (ampere), resistance (ohm), or energy (joule) are related electrical quantities but do not describe potential directly. Stating E°' without units is incorrect.
Step-by-Step Solution:
Recognize E°' as an electrical potential → unit is volts.Connect to thermodynamics: ΔG°' in joules is computed from volts via the Faraday constant and electron count.Confirm that reporting E°' values uses V or mV (e.g., +820 mV for O2/H2O).Verification / Alternative check:Standard biochemical tables list redox couples with potentials in volts or millivolts; conversions to free energy use the relationship above, reinforcing unit correctness.
Why Other Options Are Wrong:
a) Ampere measures current, not potential.c) E°' is not unitless.d) Ohm measures resistance.e) Joule measures energy, not potential; energy relates to potential via charge.Common Pitfalls:Confusing potential with energy; forgetting that reported biochemical potentials are adjusted to pH 7 (hence the double prime).
Final Answer:Volt (V).