Alkyd resins are produced by reacting a polybasic acid (e.g., phthalic anhydride) with a polyhydric alcohol (e.g., glycerol). Identify the correct product class.

Difficulty: Easy

Correct Answer: Alkyd resins

Explanation:


Introduction / Context:
Polycondensation reactions between polybasic acids and polyhydric alcohols yield a family of coating resins whose performance can be tuned by oil modification and monomer selection. Recognising this chemistry is essential in paints, varnishes, and coil-coating industries.



Given Data / Assumptions:

  • Polybasic acid example: phthalic anhydride.
  • Polyhydric alcohol example: glycerol (triol).
  • Resulting resin class is tailored for coatings and varnishes.



Concept / Approach:
Alkyds are oil-modified polyesters formed by condensation of polyacids (or anhydrides) with polyols, often incorporating fatty acids or oils to enhance flexibility, flow, and drying characteristics. While unsaturated/saturated polyesters are also formed via acid-alcohol condensation, the term “alkyd” specifically denotes the oil-modified polyester systems widely used in solvent-borne and water-reducible coatings.



Step-by-Step Solution:
Map the generic reaction: polyacid + polyol → polyester backbone.Recognise the coatings context and oil modification → alkyd resin.Exclude other classes that do not match this exact industrial nomenclature.



Verification / Alternative check:
Coatings textbooks list alkyds as phthalic anhydride–glycerol based resins, frequently modified with drying oils for oxidative cure.



Why Other Options Are Wrong:
Unsaturated polyester: used for FRP with styrene crosslinking; different usage focus.Saturated polyester: film/engineering plastics; not termed “alkyd”.Amino resins: urea/melamine–formaldehyde, distinct chemistry.



Common Pitfalls:
Equating any polyester from acid-alcohol condensation with “alkyd”. Oil modification and coatings context define alkyds.



Final Answer:
Alkyd resins

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