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  • Question
  • An azeotropic solution of two liquids has boiling point lower than either of them, when it


  • Options
  • A. is saturated.
  • B. is unsaturated.
  • C. shows negative deviation from Raoult's law.
  • D. shows positive deviation from Raoult's law.

  • Correct Answer
  • shows positive deviation from Raoult's law. 


  • Stoichiometry problems


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    • 1. Size range of the colloidals particles is

    • Options
    • A. 5 - 200 milli-microns
    • B. 50 - 200 microns
    • C. 500 - 1000 microns
    • D. 10 - 50 Angstrom
    • Discuss
    • 2. With increase in the temperature of pure (distilled) water, its

    • Options
    • A. pOH decreases and pH increases.
    • B. pOH and pH both 4ecreases.
    • C. pH and pOH both increases.
    • D. pH decreases and pOH increases.
    • Discuss
    • 3. Which of the following ratios defines the recycle ratio in a chemical process?

    • Options
    • A. Gross feed stream/recycle feed stream
    • B. Recycle stream/fresh feed stream
    • C. Recycle stream/gross feed stream
    • D. None of these
    • Discuss
    • 4. For estimation of heat capacity of a solid compound, one can use

    • Options
    • A. Clayperon's equation
    • B. Gibb's equation
    • C. Kopp's rule
    • D. Trouton's rule
    • Discuss
    • 5. At 100°C, water and methylcyclohexane both have vapour pressures of 1 atm. Also at 100°C, the latent heats of vaporisation of these compounds are 40.63 kJ/mole for water and 31.55 kJ/mole for methylcyclohexane. The vapour pressure of water at 150°C is 4.69 atm. At 150°C, the vapour pressure of methylcyclohexane would be expected to be

    • Options
    • A. significantly less than 4.69 atm.
    • B. nearly equal to 4.69 atm.
    • C. significantly more than 4.69 atm.
    • D. indeterminate due to lack of data
    • Discuss
    • 6. "The heat capacity of a solid compound is approximately equal to the sum of the heat capacities of the constituent elements." This is the statement of

    • Options
    • A. Law of Petit and Dulong
    • B. Kopp's rule
    • C. Nearnst heat theorem
    • D. Trouton's rule
    • Discuss
    • 7. 1 kg/cm2 is equal to

    • Options
    • A. 760 torr
    • B. 1KPa
    • C. 10 metres of water column
    • D. 1 metre of water column
    • Discuss
    • 8. Isotonic solutions must have the same

    • Options
    • A. viscosity
    • B. molar concentration
    • C. normality
    • D. critical temperature
    • Discuss
    • 9. Which equation is not an equation of state?

    • Options
    • A. PV = RT + B/V + y/V2 + ....
    • B. (P + a/V2)(V-b) = RT
    • C.
    • D.
    • Discuss
    • 10. One kg of saturated steam at 100°C and 1.01325 bar is contained in a rigid walled vessel. It lias a volume of 1.673 m3. It cools to 98°C ; the saturation pressure is 0.943 bar ; one kg of water vapour under these conditions has a volume of 1.789 m3. The latent heat of condensation (kJ/kg-1 ) under these conditions is

    • Options
    • A. 40732
    • B. 2676
    • C. 2263
    • D. 540
    • Discuss


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