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Home Chemical Engineering Stoichiometry Comments

  • Question
  • For estimation of heat capacity of a solid compound, one can use


  • Options
  • A. Clayperon's equation
  • B. Gibb's equation
  • C. Kopp's rule
  • D. Trouton's rule

  • Correct Answer
  • Kopp's rule 


  • Stoichiometry problems


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    • 1. At 100°C, water and methylcyclohexane both have vapour pressures of 1 atm. Also at 100°C, the latent heats of vaporisation of these compounds are 40.63 kJ/mole for water and 31.55 kJ/mole for methylcyclohexane. The vapour pressure of water at 150°C is 4.69 atm. At 150°C, the vapour pressure of methylcyclohexane would be expected to be

    • Options
    • A. significantly less than 4.69 atm.
    • B. nearly equal to 4.69 atm.
    • C. significantly more than 4.69 atm.
    • D. indeterminate due to lack of data
    • Discuss
    • 2. A chemical process is said to occur under unsteady state, if the

    • Options
    • A. inventory changes do not take place.
    • B. ratio of streams entering/leaving are independent of time.
    • C. flow rates & composition both are time dependent.
    • D. none of these.
    • Discuss
    • 3. Hess's law of constant heat summation is based on conservation of mass. It deals with

    • Options
    • A. equilibrium constant.
    • B. reaction rate.
    • C. changes in heat of reaction.
    • D. none of these.
    • Discuss
    • 4. Pick out the wrong statement:

    • Options
    • A. A vapor is termed as a saturated vapor, if its partial pressure equals its equilibrium vapor pressure.
    • B. A vapor whose partial pressure is less than its equilibrium vapor pressure, is termed as a 'superheated vapor'.
    • C. The temperature at which a vapor is saturated is termed as the boiling point.
    • D. The difference between the existing temperature of a vapor and its saturation temperature (i.e. dew point) is called its 'degree of superheat'.
    • Discuss
    • 5. What is the total pressure exerted by a mixture of 0.45 kg mole of benzene, 0.44 kg mole of toluene and 0.23 kg mole of o-xylene at 100°C, if their vapor pressures at 100°C are 1340, 560 and 210 mmHg respectively?

    • Options
    • A. 756.2
    • B. 780.5
    • C. 801.5
    • D. 880.5
    • Discuss
    • 6. Which of the following ratios defines the recycle ratio in a chemical process?

    • Options
    • A. Gross feed stream/recycle feed stream
    • B. Recycle stream/fresh feed stream
    • C. Recycle stream/gross feed stream
    • D. None of these
    • Discuss
    • 7. With increase in the temperature of pure (distilled) water, its

    • Options
    • A. pOH decreases and pH increases.
    • B. pOH and pH both 4ecreases.
    • C. pH and pOH both increases.
    • D. pH decreases and pOH increases.
    • Discuss
    • 8. Size range of the colloidals particles is

    • Options
    • A. 5 - 200 milli-microns
    • B. 50 - 200 microns
    • C. 500 - 1000 microns
    • D. 10 - 50 Angstrom
    • Discuss
    • 9. An azeotropic solution of two liquids has boiling point lower than either of them, when it

    • Options
    • A. is saturated.
    • B. is unsaturated.
    • C. shows negative deviation from Raoult's law.
    • D. shows positive deviation from Raoult's law.
    • Discuss
    • 10. "The heat capacity of a solid compound is approximately equal to the sum of the heat capacities of the constituent elements." This is the statement of

    • Options
    • A. Law of Petit and Dulong
    • B. Kopp's rule
    • C. Nearnst heat theorem
    • D. Trouton's rule
    • Discuss


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